Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

新疆库车县盐水沟北铜矿床地质特征及成因探讨          下载免费PDF全文

刘传朋 《山东国土资源》2018,34(4)

盐水沟北铜矿区位于新疆库车县北部,其大地构造位置处于塔吉克-塔里木陆块区、塔里木陆块、塔里木北缘隆起、库车前陆盆地,区内构造活动强烈。铜矿床赋存于新近纪中新统康村组第一岩性段,矿体呈层状,严格受地层控制。区内共圈定10个铜矿体,矿石矿物主要为孔雀石、赤铜矿、水胆矾、自然铜等,矿体内无夹石,顶、底板围岩均为褐红色及浅红色粉质泥岩。该矿床为砂岩型铜矿床。  相似文献   

Study of irregular wave run-up over fringing reefs based on a shock-capturing Boussinesq model     

《Applied Ocean Research》2019

This paper presents the results of a parametric study of irregular wave run-up over fringing reefs using the shock-capturing Boussinesq wave model Funwave-TVD to better understand the role of fringing reefs in the mitigation of wave-driven flooding. Laboratory experiments were newly performed with a typical fringing reef profile and typical hydrodynamic conditions to validate the model. Experimental data shows irregular wave run-ups are dominated by the low-frequency motions and confirms the run-up resonant phenomenon over the back-reef slope, which has been revealed in previous numerical studies. It is demonstrated that irregular wave evolution and run-up over fringing reefs are reasonably reproduced by the present model with a proper grid size. However, the infragravity run-up height and highest 2% run-up height over the back-reef slope are under-predicted due to the underestimation of the infragravity wave height over the reef flat. The validated model was then utilized to model irregular wave transformations and run-ups under different conditions. Through a series of numerical experiments, the effects of key hydrodynamic and reef geometry parameters, including the reef flat width, water depth over the reef flat, fore-reef slope angle and back-reef slope angle, on the irregular wave run-up were investigated. Variations of spectral components of irregular wave run-ups were examined to better understand the physical process underlying the effect of each parameter.  相似文献   

Parallelization of the flow-path network model using a particle-set strategy     

Fangli Zhang 《International journal of geographical information science》2019,33(10):1984-2010

High-performance simulation of flow dynamics remains a major challenge in the use of physical-based, fully distributed hydrologic models. Parallel computing has been widely used to overcome efficiency limitation by partitioning a basin into sub-basins and executing calculations among multiple processors. However, existing partition-based parallelization strategies are still hampered by the dependency between inter-connected sub-basins. This study proposed a particle-set strategy to parallelize the flow-path network (FPN) model for achieving higher performance in the simulation of flow dynamics. The FPN model replaced the hydrological calculations on sub-basins with the movements of water packages along the upstream and downstream flow paths. Unlike previous partition-based task decomposition approaches, the proposed particle-set strategy decomposes the computational workload by randomly allocating runoff particles to concurrent computing processors. Simulation experiments of the flow routing process were undertaken to validate the developed particle-set FPN model. The outcomes of hourly outlet discharges were compared with field gauged records, and up to 128 computing processors were tested to explore its speedup capability in parallel computing. The experimental results showed that the proposed framework can achieve similar prediction accuracy and parallel efficiency to that of the Triangulated Irregular Network (TIN)-based Real-Time Integrated Basin Simulator (tRIBS).  相似文献   

深水铺管船托管架疲劳分析及动态监测点选取研究     

闫宏生  王哲  王晓波  陈永訢  孟祥伟 《海洋工程》2018,36(1):107-113

作为S型铺管作业的关键性装备,托管架长期承受着交变载荷的作用,随着海洋开发向超深水发展,结构疲劳破坏问题不容忽视。采用疲劳谱分析的方法并结合线性累积损伤理论,对托管架结构频域下的变形进行了分析,计算了正常海况下和极端海况下托管架疲劳损伤度并对疲劳寿命进行了评估。研究发现托管架在正常海况下作业符合安全要求,在极端海况下局部结构会受到破坏。并从托管架结构安全监测角度,筛选了结构疲劳分析关键点位,为监测点位的选取提供了依据。  相似文献   

基于GIS的石家庄市雾霾分析     

苏亚聪  史娟  徐爽 《北京测绘》2020,(2):233-237

为了得出雾霾气象成因机制、影响因素和时空分布特征,以石家庄市区与郊县为研究区域,将2013年9月至2016年12月石家庄市各市区、郊县的PM2.5历史监测数据中的有效数据进行了数据分析处理得到雾霾浓度数据,还有温度、降水、风速、地形和人口密度等数据,运用GIS分析的方法,模拟绘制石家庄雾霾的时空分布图、雾霾与各影响因子的专题对比图,得到雾霾形成机制的因子、雾霾的时空分布规律、雾霾季节变化特征、雾霾与地形间的关系等;运用数据分析软件OriginPro8.SR3分析雾霾浓度与风速数据、降雨数据、温度数据间的相关性。  相似文献   

2000—2015 年伊犁河谷植被覆盖时空变化特征   总被引：1，自引：0，他引：1       下载免费PDF全文

孙国军  李卫红  朱成刚  崔东  刘海军 《干旱区地理》2020,43(6):1551-1558

利用 2000—2015 年的 EOS／MODIS 数据，采用趋势分析、Hurst 指数、变异系数法对伊犁河 谷植被时空变化及未来趋势进行分析，结果显示：空间分布上，伊犁河谷植被覆盖度呈北部、南部、 东部偏高，西部、中部偏低的分布特征；时间变化上，2000—2015 年，伊犁河谷植被覆盖度波动减 小，减速为 6.25%·(10 a)^-1；区域分布上，伊犁河谷植被表现为低波动变化，波动程度中等以及下占 73.16%，波动程度高的区域占 26.84%。未来预测表明，伊犁河谷植被覆盖呈退化趋势，其中，持续 退化的面积占 57.55%，持续改善的面积占 13.51%。  相似文献   

路网约束条件下热力规则设计与试验     

杜晓  周玉秀  周琦  郑义  张俊辉  林尚纬  陈利军 《测绘通报》2020,(7):18-21

热力图是一种能直观准确展示空间观测值的有效工具，在多个领域具有广泛应用。本文在分析设定不同道路层权重、道路技术等级分类的基础上，以反距离权重、直方图均衡化、密度补偿、参数多次迭代等方法，研究构建了以热力方式展示道路网分布及发达程度的相关规则体系。热力规则通过道路赋权、路线曲面化、密度协调、图面综合等多套规则的有机结合，实现了道路网总体发达水平信息的提取与展示，并以全球地理信息资源建设项目路网成果中的亚洲和非洲部分国家数据为例，进行了信息提取与热力分布试验。  相似文献   

利用短期静态PPP结果反演海潮负荷位移     

魏国光  王琪洁  彭葳  郭良琦 《大地测量与地球动力学》2019,39(6):607-612

采用香港11个GPS测站的观测资料进行1 h、2 h、3 h和4h静态PPP解算，获得4组PPP坐标序列，利用调和分析求取11个测站处8个主要分潮的负荷位移参数（振幅和相位），将其与海潮模型计算的负荷位移参数进行对比，并比较分析PPP反演值与海潮模型值改正海潮负荷信号的效果。结果表明，垂直和水平方向上，不同PPP结果反演8个分潮的负荷位移分别具有约5 mm和7 mm的差异；PPP反演8个分潮垂向负荷位移优于全球海潮模型，但水平方向上的反演效果稍弱。  相似文献   

顾及地形起伏的无人机影像覆盖分析方法     

张衡  李骁  叶朋飞 《测绘通报》2020,(1):102-106

使用无人机实施测绘航空摄影时，由于无人机相对航高较低，地面起伏会对无人机影像的分辨率、覆盖范围、重叠度造成较大的影响，影像成果会出现分辨率不足、重叠度不够、覆盖漏洞等缺陷。针对这一情况，本文提出了一种利用数字微分正解法的计算方法，借助DEM准确计算每张影像的覆盖范围，并使用FME软件高效生成全部影像的覆盖范围。经过实际使用，验证了该方法可以在航线设计阶段准确预测并分析全部影像的覆盖范围、重叠度，因此可及时发现设计问题并调整航线。该方法可以有效减少因地形起伏造成的影像覆盖缺陷，减少返工现象，从整体上提高了作业效率。  相似文献